女,汉族,山东临沭人
教授,博士生导师
联系方式
办公地点:南京市文苑路9号南京邮电大学仙林校区材料学科楼5-316室
电话:13951951104
Email:iamhxin@njupt.edu.cn
受教育经历
2000, 09-2003, 07 北京大学,化学与分子工程学院,无机化专业博士研究生,理学博士
1991, 09-1994, 08 华东师范大学,化学系,无机化学专业硕士研究生,理学硕士
1987, 09-1991, 08 烟台师范学院,化学系,本科生,理学学士
工作经历
2005.06-至今,南京邮电大学信息材料与纳米技术研究院/材料科学与工程学院,高层次引进人才,教授,博士生导师
2012.01-2015.05, 美国华盛顿大学,化工系,研究员
2010.03-2011.12, 美国华盛顿大学,化工系,讲师
2006.12-2010.03, 美国华盛顿大学,化工系,研究助理
2006.08-2006.12日本北路先端科学技术大学院大学, 日本学术振兴会 (Japan Society for the Promotion of Science, JSPS) 研究员
2003.10-2006.08日本国立物质材料研究机构(NIMS), 日本科学技术振兴机构 (Japan Science and Technology Agency, JST) 战略创造研究推进事业 (CREST) 研究员
1997, 09-2000, 09 青岛化工学院,讲师
1994, 09-1997, 08 青岛染料研究所,助理工程师
研究方向
(1)铜基化合物薄膜太阳能电池。包括铜锌锡硫(CuZnSnS4, CuZnSnSe4, CuZnSn(S,Se)4, 简称CZTS)和铜铟镓硒(CuIn(Ga)Se4, CIGS)薄膜太阳能电池。
(2)钙钛矿太阳能电池。
(3)叠层太阳能电池。
主要研究项目
(1)科技部重点研发计划政府间国际科技创新合作重点专项,“制约铜锌锡硫太阳能电池性能的关键缺陷及其作用机制研究”,编号2019YFE0118100,2020年12月至 2023年 11月,259.00万元,项目负责人,在研。
(2)国家自然科学基金,“DMF溶液法制备高效铜铟镓硒薄膜太阳能电池:富铜吸光材料的碱金属离子掺 杂和表面后处理研究”,编号22075150,2021年1月-2024年12月,63万元,项目负责人,在研。
(3)国家自然科学基金委员会,NSFC-云南联合基金,“以云南特有金属为组元的铜基锌黄锡矿结构化合物薄膜太阳电池高效光电转换机制研究”,编号U1902218,2020年01月至 2023年 12月,223.00万元,课题负责人,在研。
(4)国家自然科学基金,“高效铜锌锡硫薄膜太阳能电池:由DMSO前驱体溶液到半导体膜材料的化学反应路径研究”,编号21571106,2016年1月-2018年12月,71万元,项目负责人,已结题。
(5)南京邮电大学引进人才科研启动基金,“铜锌锡硫薄膜太阳能电池”,编号NY215001,2015年7月-2018年6月,200万元,项目负责人,已结题。
(6)江苏省自然基金面上项目:“溶液法制备高效铜锌锡硫薄膜太阳能电池”编号:BK20161514,10万元,2016年7月-2019年6月,项目负责人,已结题。
主要学术成绩
通过溶液化学调控薄膜半导体材料的性质、提高薄膜太阳能电池效率是目前课题组的研究特色。在铜锌锡硫太阳能电池方面,研究了DMSO溶液中的化学反应,发现了由不同价态的Sn前驱化学物引起的两种截然不同的由溶液到吸收层膜的反应路径和晶粒生长机制,通过系统研究了两种晶粒生长机制对铜锌锡硫缺陷性质及其光伏性能的影响,对制约铜锌锡硫太阳电池开路电压损失的机制有了全新的认识,获得开路电压损失最小的铜锌锡硫电池。2020年创造铜锌锡硫薄膜太阳能电池中国纪录,2021年6月铜锌锡硫薄膜太阳能电池经NREL认证效率达到13%,打破2013年由IBM创造的12.6%的前世界纪录成为新的世界记录,该效率已被收录进“Best Solar Cell Efficiency”表和“Solar cell efficiency tables (Version 59”),该效率同时录入2021中国最高效率表。在铜铟镓硒薄膜太阳能电池方面,系统研究了不同溶液体系制备的前驱体膜的硒化过程中的晶粒生长过程,首次提出直接相转化晶粒生长机制,并在富铜条件下实现高效电池。在包括Energy & Environmental Society, Journal of the American Chemical Society, Advanced Materials, ACS Nano, Advanced Energy Materials, Advanced Functional Materials, Nano Energy, Chemistry of Materials,等在内的国内外知名学术期刊发表SCI论文60余篇,他人引用次数超过3600次。单篇引用次数超过100的15篇。H因子为32。授权国际专利一项,日本专利两项,中国专利7项,PCT一项。
发表论文
1. Shaotang Yu; Bingyan Li; Jingjing Jiang; Xinge Liu; Shasha Hao; Shuaiqi Han; Weibo Yan*; Hao Xin*, Solution-Processed Chalcopyrite Solar Cells: the Grain Growth Mechanism and the Effects of Cu/In Mole Ratio, Advanced Energy Materials, 2022, 2103644.
2. Chengfeng Ma; Chunxu Xiang; Xinge Liu; Bingyan Li; Xinyu Li; Shuaiqi Han; Qi Dai; Weibo Yan*; Hao Xin*, Over 12% efficient CuIn(S,Se)2 solar cell with the absorber fabricated from DMF solution by doctor-blading in ambient air, Solar RRL, 2022, 2200150.
3. Shasha Hao; Shaotang Yu; Xinge Liu; Bingyan Li; Shuaiqi Han; Hao Xin; Weibo Yan*, Wei Huang*, Effect of K Doping on the Performance of Aqueous Solution-Processed Cu(In,Ga)Se2 Solar Cell, Advanced Energy & Sustainability Research, 2022, 2200006.
4. Jinlin Wang; Jiazheng Zhou; Xiao Xu; Fanqi Meng; Chunxu Xiang; Licheng Lou; Kang Yin; Biwen Duan; Huijue Wu; Jiangjian Shi; Yanhong Luo; Dongmei Li*; Hao Xin*; Qingbo Meng*,Ge Bidirectional Diffusion to Simultaneously Engineer Back Interface and Bulk Defects in the Absorber for Efficient CZTSSe Solar Cells, Advanced Materials, 2022, 2202858.
5. Licheng Lou; Yuancai Gong; Jiazheng Zhou; Jinlin Wang; Xiao Xu; Kang Yin; Biwen Duan; Huijue Wu; Jiangjian Shi; Yanhong Luo; Dongmei Li*; Hao Xin*; Qingbo Meng*, A feasible and effective solution-processed PCBM electron extraction layer enabling the high VOC and efficient Cu2ZnSn(S, Se)4 devices, Journal of Energy Chemistry, 2022, 70, 154-161.
6. Yuancai Gong; Ruichan Qiu; Chuanyou Niu; Junjie Fu; Erin Jedlicka; Rajiv Giridharagopal; Qiang Zhu; Yage Zhou; Weibo Yan;Shaotang Yu; Jingjing Jiang; Sixin Wu*; David S. Ginger*; Wei Huang*; Hao Xin*, Ag Incorporation with Controlled Grain Growth Enables 12.5% Efficient Kesterite Solar Cell with Open Circuit Voltage Reached 64.2% Shockley-Queisser Limit, Advanced Functional Materials, 2021, 2101927.
7. Yuancai Gong, Hao Xin*, and Liming Ding*, Voc deficit in kesterite solar cells, Journal of Semiconductors, 2021, 42(10), 100201.
8. Yuancai Gong; Yifan Zhang; Qiang Zhu; Yage Zhou; Ruichan Qiu; Chuanyou Niu; Weibo Yan*; Wei Huang; Hao Xin*, Energy & Environmental Science, 2021, 14(4): 2369-2380.
9. Chuanyou Niu; Yuancai Gong; Ruichan Qiu; Qiang Zhu;Yage Zhou; Shasha Hao; Weibo Yan*; Wei Huang; Hao Xin*, Journal of Materials Chemistry A, 2021, 9, 19281-19287.
10. ShaotangYu, JgjingJiang, Shuaiqi Han, Shasha Hao, Qiang Zhu, Yuancai Gong, WeiboYan*, Wei Huang, Hao Xin* “Structure engineering of solution-processed precursor films for low temperature fabrication of CuIn(S,Se)2 solar cells”, Solar Energy, 2021, 220, 796-801.
11. Yuancai Gong; Yifan Zhang; Erin Jedlicka; Rajiv Giridharagopal; James A. Clark; Weibo Yan; Chuanyou Niu; Ruichan Qiu; Jingjing Jiang; Shaotang Yu; Sanping Wu; Hugh W. Hillhouse; David S. Ginger; Wei Huang; Hao Xin*, Science China-Materials, 2021, 64(5): 1304-1304.
12. Zilong Wang, Di Lu, Jingjing Jiang, Weibo Yan, Yuancai Gong, Sanping Wu, Yifan Zhang, Wei Huang, and Hao Xin* “In Situ Formation of Ag2MoO4 in a Ag/MoO3 Buffer Layer Enables Highly Efficient Inverted Perovskite Cell for a Tandem Structure”, ACS Applied Energy Materials 2020, 3 (10), 9742-9749.
13. Chen, J. H.; Tang, C. C.; Guo, S. G.; Wang, Z. L.; He, Z. X.; Hwang, Y.-J.; Yan, W. B.; Xin, H. and Huang W.* “High crystalline small molecule manipulates polymer-fullerene morphology and enables 20% improvement in fill factor and device performance,” Organic Electronics, 2020, 77, 105419.
14. Jiang, J. J.; Giridharagopal, R.; Jedlicka, E.; Sun, K. W.; Yu, S. T.; Wu, S. P.; Gong, Y. C.; Yan, W. B.; Ginger, D. S.;* Green, M. A.; Hao, X. J.;* Huang, W. and Xin, H.* “Highly Efficient Copper-Rich Chalcopyrite Solar Cells from DMF Molecular Solution”Nano Energy 2020, 69, 104438.
15. Romanyuk, Y. E.; Haass, S. G.; Giraldo, S.; Placidi, M.; Tiwari, D.;Fermin, D. J.; Hao, X. J.; Xin, H.; Schnabel, T.; Kauk-Kuusik, M.;Pistor, P.; Lie,S.; and Wong, L. H. “Doping and alloying of kesterites” Journal of Physics: Energy, 2019, 1, 044004.
16. Wu, S. P.; Jiang, J. J; Yu, S. T.; Gong, Y. C.; Yan, W. B.; Xin, H.* and Huang, W. “Over 12% efficient low-bandgap CuIn(S,Se)2 solar cells with the absorber processed from aqueous metal complexes solution in air” Nano Energy 2019, 62, 818-822.
17. Yu, S. T.; Gong, Y. C.; Jiang, J. J; Wu, S. P.; Yan, W. B.*; Li, X. A.; Huang, W. and Xin, H.* “Over 10% Efficient CuIn(S,Se)2 Solar Cells Fabricated From Environmentally Benign Solution in Air” Solar RRL, 2019, 1900052.
18.Yan, W.; Wang, Z.; Gong, Y.; Guo, S.; Jiang, J.; Chen J.; Tang, C.; Xia, R.; Huang, W.;∗Xin, H.* “Naphthalene-diimide selenophene copolymers as efficient solutionprocessable electron-transporting material for perovskite solar cells” Organic Electronics, 2019, 67, 208-214.
19. Hao Xin,* Weibo Yan and Samson A. Jenekhe*, “Color-Stable White Organic Light-Emitting Diodes Utilizing a BlueEmitting Electron-Transport Layer”ACS Omega, 2018, 3, 12549−12553.
20. Shigan Guo, Weibo Yan, Jianhua Chen, Chengcheng Tang, Zilong Wang, Jingjing Jiang, Hao Xin* “Synthesis of star-shaped non-fullerene acceptors and their applications in organic solar cells,” Synthetic Metals,2018, 245, 167-174.
21. Jiang, J. J.; Yu, S. T.; Gong, Y. C.; Yan, W. B.; Zhang, R.; Liu, S. J.; Huang, W. and Xin, H.*, “10.3% Efficient CuIn(S,Se)2 Solar Cells from DMF Molecular Solution with the Absorber Selenized under High Argon Pressure” Solar RRL, 2018, 1800044.
22. Yan, W.; Rao, H.; Wei, C.; Liu, Z.; Bian, Z.; Xin, H.*; Huang, W*. “Highly efficient and stable inverted planar solar cells from (FAI)x(MABr)1−xPbI2 perovskites”; Nano Energy 2017, 35, 62-70.
23. Xin, H.; Vorpahl, S. M.; Collord, A. D.; Braly, I. L.; Uhl, A. R.; Krueger, B. W.; Ginger, D. S. and Hillhouse, H. W. “Lithium-doping inverts the nanoscale electric field at the grain boundaries in Cu2ZnSn(S,Se)4 and increases photovoltaic efficiency,” Phys. Chem. Chem. Phys. 2015, 2015,17, 23859-23866.
24. Xin, H.; Katahara, J. K.; Braly I. L. and Hillhouse, H. W. “8% Efficient Cu2ZnSn(S,Se)4 Solar Cells from Redox Equilibrated Simple Precursors in DMSO” Adv. Energy Mater. 2014, DOI10.1002/aenm.201301823.
25. Collord, A. D.; Xin, H. and Hillhouse, H. W. “Combinatorial Exploration of the Effects of Intrinsic and Extrinsic Defects in Cu2ZnSn(S,Se)4”, IEEE J. Photovoltaics 2015, 5, 288-298. (IF=3.165)
26. Salvador, M.; Vorpahl, S. M.; Xin, H.; Williamson, W.; Shao, G.; Karatay, D. U.; Hillhouse, H. W.;. Ginger. D. S. “Nanoscale Surface Potential Variation Correlates with Local S/Se Ratio in Solution-Processed CZTSSe Solar Cells,”Nano Lett. 2014, 14, 6926−6930. (IF=13.592)
27. Subramaniyan, S,; Xin, H.; Kim, F. S.; Murari, N. M.; Courtright, B. A. E.; Jenekhe, S. A. “Thiazolothiazole Donor-Acceptor Conjugated Polymer Semiconductors for Photovoltaic Applications,” Macromolecules, 2014, 47, 4199-4209. (IF=5.800)
28. Xin, H. and Hillhouse, H. W. “8.3% Efficient Copper Zinc Tin Sulfoselenide Solar Cells Processed from Environmentally Benign Solvent,” Proceedings of 39th IEEE Photovoltaic Specialists Conference (PVSC) , 2013, 441-443.
29. Shoaee, S.; Subramaniyan S.; Xin, H.; Keiderling, C.; Tuladhar, P. S.; Jamieson, F., Jenekhe, S. A.; Durrant, J. R. “Charge Photogeneration for a Series of Thiazolo-Thiazole Donor Polymers Blended with the Fullerene Electron Acceptors PCBM and ICBA,”Adv. Funct. Mater. 2013, 23, 3286-3298.
30.Xin, H.; Guo, X.; Ren, G.; Watson, M. D.; Jenekhe, S. A. “Efficient Phthalimide Copolymer-Based Bulk Heterojunction Solar Cells: How the Processing Additive Influences Nanoscale Morphology and Photovoltaic Properties,” Adv. Energy Mater. 2012, 2, 575-582.
31. Xin, H; Subramaniyan, S.; Kwon, T-W.; Shoaee, S.; Durrant, J. R; Jenekhe, S. A. “Enhanced Open Circuit Voltage and Efficiency of Donor-Acceptor Copolymer Solar Cells by Using Indene-C60 Bisadduct,” Chem. Mater. 2012, 24, 1995-2001.
32. Hwang, Y. J.; Kim, F. S.; Xin, H.; Jenekhe, S. A. “New Thienothiadiazole-Based Conjugated Copolymers for Electronics and Optoelectronics,” Macromolecules 2012, 45, 3732-3739.
33. Lee, H. J.; Xin, H.; Park, S. M.; Park, S. I.; Ahn, T.; Park, D. K.; Jenekhe, S. A.; Kwon, T. W. “Synthesis and Properties of Diarylamino-Substituted Linear and Dendritic Oligoquinolines for Organic Light-Emitting Diodes,” Bulletin Korean Chem. Soc. 2012, 33, 1627-1637.
34.Subramaniyan, S.; Xin, H.; Kim, F. S.; Shoaee, S.; Durrant, J. R.; Jenekhe, S. A. “Effects of Side Chains on Thiazolothiazole-Based Copolymer Semiconductors for High Performance Solar Cells,” Adv. Energy Mater. 2011, 5, 854-860.
35.Guo, X.; Xin, H.; Kim, F. S.; Liyanage, A. D. T.; Jenekhe, S. A.; Watson, M. D. “Thieno[3,4-c]pyrrole-4,6-dione-Based Donor-Acceptor Conjugated Polymers for Solar Cells,” Macromolecules 2011, 44,: 269-277.
36. Subramaniyan, S.; Xin, H.; Kim, F. S.; Jenekhe, S. A. “New Thiazolothiazole Copolymer Semiconductors for Highly Efficient Solar Cells,” Macromolecules 2011, 44, 6245-6248.
37. Ahmed, E.; Subramaniyan, S.; Kim, F. S.; Xin, H.; Jenekhe, S. A. “Benzobisthiazole-Based Donor-Acceptor Copolymer Semiconductors for Photovoltaic Cells and Highly Stable Field-Effect Transistors,” Macromolecules, 2011, 44, 7207-7219.
38. Xin, H.; Reid, O. G.; Ren, G.; Kim, F. S.; Ginger, D. S.; Jenekhe, S. A. “Polymer Nanowire/Fullerene Bulk Heterojunction Solar Cells: How Nanostructure Determines Photovoltaic Properties,” ACS Nano, 2010, 4, 1861-1872.
39. Reid, Obadiah G.; Xin, H.; Jenekhe, Samson A.; Ginger, David S. “Nanostructure determines the intensity-dependence of open-circuit voltage,” J. Appl. Phys. 2010, 108, 084320.
40. Xin, H.; Guo, X. G.; Kim, F. S.; Ren, G.; Watson, M. D.; Jenekhe, S. A. “Efficient Solar Cells Based on a New phthalimide-based Donor-Acceptor Copolymer semiconductor: Morphology, Charge-Transport, and Photovoltaic Performance,” J. Mater. Chem. 2009, 19, 5303-5310.
41.Wu, P-T; Xin, H.; Kim, F. S.; Ren, G.; Jenekhe, S. A. “Regioregular Poly(3-pentylthiophene): Synthesis, Self-Assembly of Nanowires, High-Mobility Field-Effect Transistors, and Efficient Photovoltaic Cells,” Macromolecule 2009, 42, 8817-8826.
42. Ahmed, E.; Kim, F. S.; Xin, H.; Jenekhe, S. A. “Benzobisthiazole-Thiophene Copolymer Semiconductors: Synthesis, Enhanced Stability, Field-Effect Transistors, and Efficient Solar Cells,” Macromolecule 2009, 42, 8615-8618.
43.Geng, F.; Matsushita, Y.; Ma, R.; Xin, H.; Tanaka, M.; Iyi, N.; Sasaki, T. “Synthesis and Properties of Well-Crystallized Layered Rare-Earth Hydroxide Nitrates from Homogeneous Precipitation,” Inorg. Chem. 2009, 48, 6724–6730.
44. Xin, H.; Kim, F. S.; Jenekhe, S. A. “Highly efficient solar cells based on poly(3-butylthiophene) nanowires,” J. Am. Chem. Soc. 2008, 130, 5424-5425.
45. Xin, H.; Ren, G.; Kim, F. S.; Jenekhe, S. A. “Bulk Heterojunction Solar Cells from Poly(3-butylthiophene)/Fullerene Blends: In Situ Self-Assembly of Nanowires, Morphology, Charge Transport, and Photovoltaic Properties,” Chem. Mater. 2008, 20, 6199-6207.
46. Geng, F.; Xin, H. (first coauthor); Matsushita, Y.; Ma, R.; Tanaka, M.; Izumi, F.; Iyi, N.; Sasaki, T. “New layered rare-earth hydroxides with anion-exchange properties,” Chem. Eur. J. 2008, 14, 9255-9260.
47. Geng, F.; Matsushita, Y.; Ma, R.; Xin, H.; Tanaka, M.; Izumi, F.; Iyi, N.; Sasaki, T. “General Synthesis and Structural Evolution of a Layered Family of Ln8(OH)20Cl4nH2O (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Y),” J. Am. Chem. Soc. 2008, 130, 16344-16350.
48. Xin, H.; Ebina, Y.; Ma, R.; Takada, K.; Sasaki, T. “Thermally stable luminescent composites fabricated by confining rare earth complexes in the two-dimensional gallery of titania nanosheets and their photophysical properties,” J. Phys. Chem. B. 2006, 110, 9863-9868.
49.Xin, H.; Ma, R.; Wang, L.; Ebina, Y.; Takada, K.; Sasaki, T. “Photoluminescence Properties of Lamellar Aggregates of Titania Nanosheets Accommodating Rare Earth Ions,” Appl. Phys. Lett. 2004, 85, 4187-4189.
50. Xin, H.; Shi, M.; Gao, X. C.; Huang, Y. Y.; Gong, Z. L.; Nie, D. B.; Cao, H.; Bian, Z. Q.; Li, F. Y.; Huang, C. H. “The Effect of Different Neutral Ligands on Photoluminescence and electroluminescence Properties of Ternary Terbium Complexes,” J. Phys. Chem. B. 2004, 108, 10796-10800.
51. Xin, H.; Sun, M.; Wang, K. Z.; Zhang, Y. A.; Jin, L. P.; Huang, C. H. “Voltage-independent pure red devices based on a carbazole-functionalized europium complex,” Chem. Phys. Lett. 2004, 388, 55-57.
52. Bian, Z. Q.; Gao, D. Q.; Guan, M.; Xin, H.; Li, F. Y.; Huang, C. H.; Wang, K. Z.; Jin, L. P. “Electroluminescent properties of three ternary europium complexes with different phenanthroline derivatives,” Science in China Series B-Chem. 2004, 47, 326-334.
53. Gao, D. Q.; Guan, M.; Xin, H.; Bian, Z. Q.; Huang, C. H. “Photoluminescence and electroluminescence properties of ligand emitting Y3+, La3+, Gd3+ and Lu3+ complexes,” J. Rare Earths 2004, 22, 206-209.
54. Xin, H.; Li, F. Y.; Bian, Z. Q.; Huang, C. H. “Efficient Electroluminescence from a New Terbium Complex,” J. Am. Chem. Soc. 2003, 125, 7166-7167.
55. Xin, H.; Shi, M.; Li, F. Y.; Zhang, X. M.; Bian, Z. Q.; Ibrahim, K.; Liu, F. Q.; Huang, C. H. “Carrier-Transport, Photoluminescence and Electroluminescence Properties Comparison of a Series Terbium Complex with Different Structure,” Chem. Mater. 2003, 15, 3728-3733.
56. Xin, H.; Sun, M.; Wang, K. Z.; Zhang, Y. A.; Jin, L. P.; Guan, M.; Huang, C. H. “Carbazole-Functionalized Europium Complex and Its light-Emitting Properties,” J. Appl. Phys. 2003, 94, 4729-4731.
57.Xin, H.; Shi, M.; Li, F. Y.; Gao, D. Q.; Huang, C. H. “Photoluminescence and Electroluminescence of Three Ternary Lutetium Complexes,” New J. Chem. 2003, 27, 1485-1489.
58. Sun, M.; Xin, H.; Wang, K. Z.; Zhang, Y. A.; Jin, L. P.; Huang, C. H. “Bright and monochromic red light-emitting electroluminescence devices based on a new multifunctional europium ternary complex,” Chem. Commun. 2003, 702-703.
59. Sun, M.; Xin, H.; Zhang, Y. A.; Wang, K. Z. “Synthesis, Characterization and Photoelectric Properties of a Novel Carbazol-Containing Re (II) Complex,” Huaxue Xuebao 2003, 61, 1323-1325.
60. Guan, M.; Bian, Z. Q. Li, F. Y.; Xin, H.; Huang, C. H. “Bright red light-emitting electroluminescence devices based on a functionalized europium complex,” New J. Chem. 2003, 27, 1731-1734.
61.Xin, H.; Guan, M.; Li, F. Y.; Bian, Z. Q.; Huang, C. H.; Ibrahim, K.; Liu, F. Q. “Photoluminescence and electroluminescence of the exciplex formed between a terbium ternary complex and N, N’-bis(3-methylphenyl)-1,1’-diphenyl -4,4’-diamine,” Phys. Chem. Chem. Phys. 2002, 4, 5895-5898.
62. Xin, H.; Li, F. Y.; Huang, Y. Y.; Huang, C. H. “Self-assembled Film of Tb3+ and Poly(3-Thiophene Acetic Acid) via Layer-by-Layer Complexation Technique and Its Photoluminescence,” J. Rare Earths. 2002, 22, 333-338.
授权及申请中专利
PATENTS
1. Title: Solar Cells Based on Polymer Nanowires
Patent No. US 20090235988
Inventors: Jenekhe, Samson A.; Xin, Hao; Kim, Felix Sunjoo.
2.Title: Phospher Material, Method for Producing the same and Light-Emitting Device
Patent No. JP 2006291119
Inventors: Sasaki, Takayoshi; Xin, Hao; Ebina, Yasuo; Ma, Renzhi.
3. Title: Layered Rare Earth Hydroxide and Anion-Exchange Material and Fluorescent Material using it Patent No. JP 2009184868
Inventors: Sasaki, Takayoshi; Geng, Fengxia; Xin, Hao; Ma, Renzhi
4. Title: Terbium Compound Electroluminescence Material and Device
Patent No. CN1534024
Inventors: Huang, ChunHui; Xin, Hao; Li, Fuyou.
5. 前驱体溶液及其制备银铜锌锡硫薄膜太阳能电池的方法,发明专利,专利申请号:2020112818562, 2020-11-17。
6. 铜锌锡硫薄膜太阳能电池的前驱体溶液及其制备方法与应用, PCT,专利申请号:PCT/CN2020/121966,2020-10-19。
7. 铜锌锡硫薄膜太阳能电池的前驱体溶液及其制备方法与应用, 发明专利,专利申请号:2020104109314,2020-05-15。
8. 一种用于叠层电池透明电极的高透过率缓冲层结构的制备方法,发明专利,专利申请号:201910796855.2,2019-08-27。
9. 基于萘酰亚胺-硒吩衍生物的有机n型半导体聚合物材料及其制备方法与应用,发明专利,专利申请号;201910341859.1,2019-04-26。
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